ASTM B338

Gr1 Gr2 Gr7 Gr9 Gr12 Heat Exchanger Tubing

ASTM B338 standard titanium heat exchanger tubing, seamless and welded types, multiple alloy grades for power, chemical, desalination and marine heat transfer equipment.

Item Standard Details
Standard Designation ASTM B338-17(R21), Equivalent ASME SB338
Full Standard Name Standard Specification for Seamless and Welded Titanium and Titanium Alloy Tubes for Condensers and Heat Exchangers
Issuing Organization ASTM International
Revision & Reapproval Date July 13, 2017; Reapproved 2021
ICS Code 23.040.15
Document Pages 9 Official Standard Pages

1.1 This specification covers the requirements for 28 grades of titanium and titanium alloy tubing intended for surface condensers, evaporators, and heat exchangers. Two manufacturing forms are defined: seamless tube and welded tube.

1.2 The values stated in inch-pound units are standard; SI unit conversions in parentheses are provided for reference only and shall not be regarded as mandatory.

1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the WTO Technical Barriers to Trade (TBT) Committee.

Grade No. UNS Number Material Composition Description
Grade 1 R50250 Unalloyed pure titanium, low oxygen content
Grade 2 / Grade 2H R50400 General pure titanium; 2H = high tensile strength variant for pressure vessels
Grade 3 R50550 Higher strength unalloyed titanium
Grade 7 / Grade 7H R52400 Ti + 0.12~0.25% Palladium; H = high strength grade
Grade 9 R56320 Ti-3Al-2.5V medium strength titanium alloy
Grade 11 R52250 Ti + 0.12~0.25% palladium
Grade 12 R53400 Ti-0.3Mo-0.8Ni anti-corrosion alloy
Grade 13 R53413 Ti-0.5Ni-0.05Ru
Grade 14 R53414 Ti-0.5Ni-0.05Ru
Grade 15 R53415 Ti-0.5Ni-0.05Ru
Grade 16 / Grade 16H R52402 Ti + 0.04~0.08% palladium; high strength H version
Grade 17 R52252 Ti + 0.04~0.08% palladium
Grade 18 R56322 Ti-3Al-2.5V + 0.04~0.08% palladium
Grade 26 / Grade 26H R52404 Ti + 0.08~0.14% ruthenium; H high tensile variant
Grade 27 R52254 Ti + 0.08~0.14% ruthenium
Grade 28 R56323 Ti-3Al-2.5V + 0.08~0.14% ruthenium
Grade 30 R53530 Ti-0.3Co-0.05Pd
Grade 31 R53532 Ti-0.3Co-0.05Pd
Grade 33 R53442 Ti-0.4Ni-0.015Pd-0.025Ru-0.15Cr
Grade 34 R53445 Ti-0.4Ni-0.015Pd-0.025Ru-0.15Cr
Grade 35 R56340 Ti-4.5Al-2Mo-1.6V-0.5Fe-0.3Si
Grade 36 R58450 Ti-45Niobium alloy
Grade 37 R52815 Ti-1.5Al low alloy titanium
Grade 38 R54250 Ti-4Al-2.5V-1.5Fe
Grade 39 R53390 Ti-0.25Fe-0.4Si

Note: H suffix grades share identical chemical composition with base grades, with higher minimum tensile strength (58 ksi / 400 MPa), specially designed for pressure vessel equipment.

Seamless Titanium Tube

  • Raw material: solid titanium hollow billet
  • Process flow: hot extrusion → multi-pass cold drawing → full annealing finishing
  • Advantage: zero weld defects, uniform wall, high pressure resistance
  • Application: high purity & high pressure heat exchange equipment

Welded Titanium Tube

  • Raw material: flat titanium strip coil
  • Process: GTAW automatic welding → cold sizing → stress relief annealing
  • Weld requirement: weld grain recrystallized after cold forming
  • Mandatory 100% triple non-destructive inspection

TABLE 1 Chemical RequirementsA

Element Grade 1 Grade 2 Grade 3 Grade 7 Grade 9 Grade 11 Grade 12
Nitrogen, max 0.03 0.03 0.05 0.03 0.03 0.03 0.03
Carbon, max 0.08 0.08 0.08 0.08 0.08 0.08 0.08
Hydrogen,B,C max 0.015 0.015 0.015 0.015 0.015 0.015 0.015
Iron, max 0.20 0.30 0.30 0.30 0.25 0.20 0.30
Oxygen, max 0.18 0.25 0.35 0.25 0.15 0.18 0.25
Aluminum 2.5–3.5
Vanadium 2.0–3.0
Tin
Ruthenium
Palladium 0.12–0.25 0.12–0.25
Cobalt
Molybdenum 0.2–0.4
Chromium
Nickel 0.6–0.9
Niobium
Zirconium
Silicon
Residuals,D,E,F max each 0.1 0.1 0.1 0.1 0.1 0.1 0.1
Residuals,D,E,F max total 0.4 0.4 0.4 0.4 0.4 0.4 0.4
TitaniumG balance balance balance balance balance balance balance

TABLE 1 Continued

Element Grade 13 Grade 14 Grade 15 Grade 16 Grade 17 Grade 18 Grade 26
Nitrogen, max 0.03 0.03 0.05 0.03 0.03 0.03 0.03
Carbon, max 0.08 0.08 0.08 0.08 0.08 0.08 0.08
Hydrogen,B,C max 0.015 0.015 0.015 0.015 0.015 0.015 0.015
Iron, max 0.20 0.30 0.30 0.30 0.20 0.25 0.30
Oxygen, max 0.10 0.15 0.25 0.25 0.18 0.15 0.25
Aluminum 2.5–3.5
Vanadium 2.0–3.0
Ruthenium 0.04–0.06 0.04–0.06 0.04–0.06 0.08–0.14
Palladium 0.04–0.08 0.04–0.08 0.04–0.08
Nickel 0.4–0.6 0.4–0.6 0.4–0.6
Residuals,D,E,F max each 0.1 0.1 0.1 0.1 0.1 0.1 0.1
Residuals,D,E,F max total 0.4 0.4 0.4 0.4 0.4 0.4 0.4
TitaniumG balance balance balance balance balance balance balance

TABLE 2 Continued

Element Grade 27 Grade 28 Grade 30 Grade 31 Grade 33 Grade 34 Grade 35 Grade 36
Nitrogen, max 0.03 0.03 0.03 0.05 0.03 0.05 0.05 0.03
Carbon, max 0.08 0.08 0.08 0.08 0.08 0.08 0.08 0.04
Hydrogen,B,C max 0.015 0.015 0.015 0.015 0.015 0.015 0.015 0.0035
Iron, max or range 0.20 0.25 0.30 0.30 0.30 0.30 0.20–0.80 0.03
Oxygen, max 0.18 0.15 0.25 0.35 0.25 0.35 0.25 0.16
Aluminum 2.5–3.5 4.0–5.0
Vanadium 2.0–3.0 1.1–2.1
Ruthenium 0.08–0.14 0.08–0.14 0.02–0.04 0.02–0.04
Palladium 0.04–0.08 0.04–0.08 0.01–0.02 0.01–0.02
Cobalt 0.20–0.80 0.20–0.80
Molybdenum 1.5–2.5
Chromium 0.1–0.2 0.1–0.2
Nickel 0.35–0.55 0.35–0.55
Niobium 42.0–47.0
Silicon 0.20–0.40
Residuals,D,E,F max each 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1
Residuals,D,E,F max total 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4
TitaniumG balance balance balance balance Remainder Remainder Remainder Remainder

A Analysis shall be completed for all elements listed in this table for each grade. The analysis results for the elements not quantified in the table need not be reported unless the concentration level is greater than 0.1 % each or 0.4 % total.

B Lower hydrogen may be obtained by negotiation with the manufacturer.

C Final product analysis.

D Need not be reported.

E A residual is an element present in a metal or an alloy in small quantities and is inherent to the manufacturing process but not added intentionally. In titanium these elements include aluminum, vanadium, tin, chromium, molybdenum, niobium, zirconium, hafnium, bismuth, ruthenium, palladium, yttrium, copper, silicon, cobalt, tantalum, nickel, boron, manganese, and tungsten.

F The purchaser may, in his written purchase order, request analysis for specific residual elements not listed in this specification.

G The percentage of titanium is determined by difference.

Grade Tensile Strength, min Yield Strength, 0.2% Offset Elongation
in 2 in (50 mm),
min, %
ksi MPa min ksi min MPa max ksi max MPa
1A 35 240 25 170 45 310 24
2A 50 345 40 275 65 450 20
3A 65 450