ASTM A532 Class II and III
ASTM A532 Class II, Ni-Hard 2 and 3 High Chrome White Iron, Nickel-Chrome-High Carbon Alloy

ASTM A532 specification covers a group of high chrome white cast irons engineered for superior abrasion resistance.

While Class I (including Ni-Hard 1) represents the earliest generation of wear-resistant alloys, Class II and Class III offer significantly improved performance through higher chromium content and optimized microstructures. These advanced alloys are widely used in demanding industries such as oil sands, mining, recycling, and hydraulic fracturing where severe wear conditions exist.

Note: The high chromium content in these alloys promotes the formation of hard carbides in the microstructure, providing exceptional wear resistance compared to conventional cast irons.

ASTM A532 Class II (Chromium-Molybdenum White Irons)

Class II alloys contain 11-23% chromium and up to 3.5% molybdenum, creating a balance between hardness and impact resistance. The molybdenum addition helps maintain hardness while improving toughness compared to higher chromium variants.

Key Types:

Class II Type B (15-3)

Composition

  • Chromium: 14-18%
  • Carbon: 2.4-3.0%
  • Molybdenum: up to 3%

Distinctive Properties

  • Moderate carbide content providing balanced wear resistance and toughness
  • Excellent for applications requiring impact resistance with good wear properties

Applications

Ball mill liners, dredging components, roller crushers

Class II Type D (20-1)

Composition

  • Chromium: 18-25%
  • Carbon: 2.8-3.1%
  • Molybdenum: up to 1.5%

Physical Properties

  • Density: 0.26 lb/in³ (7.6 g/cm³)
  • Thermal Conductivity: 8.6-17.3 Btu/hr·ft·F (15-30 W/m·K)
  • Melting Temperature: 2300°F

Mechanical Properties

  • Compressive Strength: 429 Ksi (2960 MPa)
  • Transverse Strength: 136 Ksi (938 MPa)
  • Hardness: 450-550 BHN as-cast, >650 BHN when hardened

Key Advantages

  • Combines high hardness with improved toughness
  • Good machinability for facing and fitting (cannot be drilled/tapped)
  • Suitable for thicker section castings

Applications

Mining crusher components, chute liners, crushing bars, anvils

ASTM A532 Class III (High-Chromium White Irons)

Class III alloys represent the premium tier of abrasion-resistant cast irons, containing 23-30% chromium. These alloys form complex chromium carbides in their microstructure, providing exceptional wear resistance and good corrosion properties.

Class III Type A Standard Properties

Composition
  • Carbon: 2.0-3.3%
  • Chromium: 23-30%
  • Manganese: ≤2.0%
  • Silicon: ≤1.5%
Microstructure

High volume fraction of chromium-rich M₇C₃ carbides in a martensitic or austenitic matrix

General Characteristics: Excellent abrasion resistance with good corrosion properties

Specialized Variants

Pliant25

Unique Feature

Can be temporarily softened for machining operations

Processing

Supplied soft for drilling, tapping, and broaching, then hardened to >600 BHN

Best Applications

Precision components requiring machining (pump volutes, impellers, liners)

Granite25

Hardness

Consistently >650 BHN

Position

Most widely used Class III alloy

Applications

Universal wear solution for slurry pumping, crushing, and general abrasion resistance

Diamond25

Distinctive Quality

Highest carbide volume fraction

Hardness

Exceeds 680 BHN

Best For

Extreme abrasion environments in mining and recycling (chute liners, blow bars)

Tough25

Engineered For

Enhanced toughness in thick sections

Applications

Gyratory crushers and pulverizers where impact resistance is critical

30% Cr

Key Attribute

Maximum corrosion resistance among ASTM A532 alloys

Trade-off

Slightly reduced abrasion resistance compared to other Class III variants

Specialized Use

Flue-gas desulfurization and corrosive environments

Comparative Analysis: Class II vs. Class III

Property Class II Class III
Chromium Content 11-23% 23-30%
Carbide Structure Mixed carbides Predominantly M₇C₃ chromium-rich carbides
Hardness Range 450-650+ BHN 600-680+ BHN
Corrosion Resistance Good Excellent (especially 30% Cr variant)
Toughness Better impact resistance Optimized for abrasion resistance
Cost Moderate Higher
Best Applications Moderate impact with abrasion Severe abrasion environments

Processing Considerations

Heat Treatment Options

Both Class II and Class III alloys are frequently supplied in the following conditions:

  1. Annealed State: Often delivered with maximum 400 HB hardness for machinability
  2. Heat Treatment Options:
    • As-cast
    • Stress relieved
    • Hardened (typically after machining)
    • Hardened and stress relieved
Manufacturing Notes:
  • Class II Type D can be machined and faced but not drilled or tapped
  • Class III Pliant25 offers unique machinability before final hardening
  • Thick sections may require special heat treatment to ensure through-hardening

Industry Applications

Industry Typical Components Preferred Alloy Class
Mining Crusher liners, grinding mills Class III (Diamond25, Tough25)
Oil Sands Slurry pumps, hydrotransport Class III (Granite25)
Cement Grinding tables, rollers Class II Type B or D
Recycling Hammers, blow bars Class III (Diamond25)
Power Generation Coal pulverizers, ash handling Class II or III depending on conditions
Dredging Pump components, cutters Class II Type B
Hydraulic Fracturing Fluid end components Class III (Pliant25)

Selection Guidance

When choosing between Class II and Class III alloys, consider:
  1. Wear Mechanism: For pure abrasion, Class III is superior; for impact-abrasion, Class II may be preferable
  2. Section Thickness: Thicker sections may benefit from Class II or specialized Class III (Tough25)
  3. Corrosion Requirements: For corrosive environments, 30% Cr variant of Class III is optimal
  4. Machining Needs: If complex machining is required, Pliant25 (Class III) offers unique advantages
  5. Cost Considerations: Class II typically offers lower cost with good performance in moderate wear applications

ASTM A532 Class I Type A vs Class II Type D Comparison

Class I Type A (Ni-Cr-HC)

  • Chromium Content: 15-18%
  • Nickel Content: 0.5-1.0%
  • Hardness: ≥63 HRC

Class II Type D (Cr-Mo-HC)

  • Chromium Content: 20-28%
  • Molybdenum Content: 1.5-3.0%
  • Hardness: ≥58 HRC

Technical Comparison

Feature Class I Type A Class II Type D
Primary Alloy Elements Nickel-Chromium System Chromium-Molybdenum System
Impact Resistance Higher (Composite Structure) Standard
Corrosion Resistance Superior Moderate
Typical Applications Mining crushers, Cement plants Coal handling, Power generation

Selection Guidelines:

  • Choose Class I Type A for applications requiring combined abrasion resistance and corrosion protection
  • Prefer Class II Type D for pure abrasion environments with impact loading

Microstructure Characteristics

Class I Type A

Martensitic matrix with chromium carbides and nickel-enhanced toughness

Class II Type D

Hyper-eutectic structure with molybdenum-stabilized carbides

ASTM A532 Class II Type D (Cr-Mo-HC) Technical Data Sheet

Material Classification

  • Standard: ASTM A532/A532M
  • Class: II
  • Type: D (Cr-Mo-HC)
  • Material Type: Abrasion-Resistant White Cast Iron

Mechanical Properties

Property Value Test Method
Hardness ≥58 HRC / 650 BHN ASTM E18
Impact Strength 15-25 J/cm² ASTM E23
Service Temperature Up to 450°C (842°F) ASTM E21

Chemical Composition (%)

C Cr Mo Mn Si P S
2.8-3.6 20-28 1.5-3.0 ≤1.5 ≤1.0 ≤0.10 ≤0.15

* May contain trace elements of Ni, Cu

Typical Applications

  • Coal handling equipment
  • Power plant components
  • Mining conveyor systems
  • Cement mill liners

Cross-Standard Equivalents

ISO 21988/GX260CrMo27-1
DIN 1695-81
JIS G5151-SCMnH3

Recommended Heat Treatment

  • Stress Relieving: 500-550°C for 2-4 hours
  • Hardening: Air cooling from 950-1000°C
  • Tempering: 200-300°C for improved toughness

【H】 Ceramic lined pipe

Ceramic lined pipe is made through self-propagating high-temperature synthesis (SHS) technique.

【H】 Cast basalt lined steel pipe

Cast basalt lined steel pipe is composed by lined with cast basalt pipe, outside steel pipe and cement mortar filling between the two layers.

【H】 Ceramic Tile Lined Pipes

Ceramic tile lined pipes have very uniform coating of specially formulated ceramic material that is affixed to the inner of the pipe.

【H】 Rare earth alloy wear-resistant pipe

The material of the rare earth alloy wear-resistant pipe is ZG40CrMnMoNiSiRe, which is also the grade of rare earth alloy steel.

【H】 Tubes Erosion Shields

Tubes Erosion Shields are used to protect boiler tubing from the highly erosive effects of high temperatures and pressures thereby greatly extending tube life.

【H】 ASTM A213 T91 Alloy Tube

The ASTM A213 T91 seamless tubes are primarily used for boiler, superheater, and heat-exchanger.

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