Duplex 2205 (UNS S31803)

Duplex 2205 is a type of stainless steel that belongs to the family of duplex stainless steels.

The high amounts of molybdenum and chromium content in 2205 offer strength, improved pitting and consistent stress corrosion cracking resistance. 2205 integrates the best features of austenitic and ferritic steels (as well as nearly equal amounts of austenite and ferrite) and can be welded with common stainless steel welding techniques – its uniform composition minimizes localized corrosion.

Duplex 2205 stainless steel, also known as UNS S32205 (formerly UNS S31803), is a type of stainless steel that is characterized by a mixed microstructure of austenite and ferrite, offering a combination of high strength and excellent corrosion resistance.

Specifications - Duplex 2205

Avesta Sheffield 2205 is a ferritic-austenitic stainless steel which combines many of the beneficial properties of both ferritic and austenitic steels. As a result of high chromium and molybdenum contents, the steel has very good pitting and uniform corrosion resistance, as well as high mechanical strength. 2205 has good weldability and can be welded using most of the techniques for stainless steels. Due to the balanced composition, when welded correctly, the heat-affected zone contains sufficient austenite to avoid risk of localized corrosion.

Key Properties

What is Duplex 2205?

Duplex 2205 is a two-phase, ferritic, austenitic 22% chromium, 3% molybdenum, 5 to 6% nickel alloyed stainless steel. It is the most widely used duplex stainless steel grade and is characterized by high yield strength, double that of the standard austenitic stainless steel grades.

Duplex 2205 is a type of stainless steel that belongs to the family of duplex stainless steels, which are designed to have a combination of high strength and excellent corrosion resistance. Duplex 2205 is composed of a mixture of austenitic and ferritic phases, providing superior mechanical and corrosion resistance properties compared to traditional austenitic stainless steels.

Duplex 2205 has several advantages over other types of stainless steel, including:

Excellent corrosion resistance: Duplex 2205 offers superior resistance to pitting, crevice corrosion and stress-corrosion cracking compared to traditional austenitic stainless steels.

High strength: Duplex 2205 has higher strength than most other types of stainless steel, particularly in terms of its yield and tensile strength.

Good weldability: Duplex 2205 can be easily welded using conventional welding techniques, without affecting the properties of the material.

Good machinability: Duplex 2205 is relatively easy to machine, despite being a duplex stainless steel.

Duplex 2205 is commonly used in various industries such as chemical processing, oil and gas, pulp and paper, and marine applications. It is particularly suitable for use in corrosive environments where high strength and good corrosion resistance are required.

Overall, Duplex 2205 is an important material that offers a combination of strength, corrosion resistance, and ease of fabrication, making it a popular choice for various industrial applications.

What is the difference between duplex 2205 and 316 SS?

Generally, 2205 duplex stainless steel tends to be more expensive than 316 due to its unique composition and superior properties. The higher chromium, molybdenum, and nitrogen content, as well as the dual-phase microstructure, contribute to its higher cost.

Applications

Chemical Composition - Duplex 2205

C Cr Fe Mn Mo N Ni P S Si
Max        Max          Max Max Max
.03% 22%-23% BAL 2.0% 3.0% -3.5% .14% - .2% 4.5%-6.5% .03% .02% 1%

Design Features - Duplex 2205

Typical Applications - Duplex 2205

Some of the typical applications of duplex steel grade 2205 are listed below:

Physical Properties

The physical properties of grade 2205 stainless steels are tabulated below.

Grade Density
(kg/m3)
Elastic
Modulus
(GPa)
Mean Co-eff of Thermal
Expansion (μm/m/°C)
Thermal
Conductivity (W/m.K)
Specific
Heat
0-100°C
 ( J/kg.K)
Electrical
Resistivity
(nΩ.m)
0-100°C 0-315°C 0-538°C at 100°C at 500°C
2205 782 190 13.7 14.2 - 19 - 418 850

Corrosion Resistance

Grade 2205 stainless steel exhibits excellent corrosion resistance, much higher than that of grade 316. It resists localized corrosion types like intergranular, crevice and pitting. The CPT of this type of stainless steel is around 35°C. This grade is resistant to chloride stress corrosion cracking (SCC) at temperatures of 150°C. Grade 2205 stainless steels are apt replacements to austenitic grades, especially in premature failure environments and marine environments.

The super duplex gradesare even more resistant to corrosion.

Heat Resistance

Fabrication

Fabrication of all stainless steelsshould be done only with tools dedicated to stainless steel materials. Tooling and work surfaces must be thoroughly cleaned before use. These precautions are necessary to avoid cross contamination of stainless steel by easily corroded metals that may discolour the surface of the fabricated product.

Welding

Most standard welding methods suit this grade, except welding without filler metals, which results in excess ferrite. AS 1554.6 pre-qualifies welding for 2205 with 2209 rods or electrodes so that the deposited metal has the right balanced duplex structure.

Adding nitrogen to the shielding gas ensures that adequate austenite is added to the structure. The heat input must be maintained at a low level, and the use of pre or post heat must be avoided. The co-efficient of thermal expansion for this grade is low; hence the distortion and stresses are lesser than that in austenite grades.

Machinability

Although machinable, the high strengths of duplex stainless steels makes machining difficult. As an example, machining of 2205 is around 20% slower than for 304.

Machining can be enhanced by using the following rules:

Heat Treatment

Duplex stainless steelscannot be hardened by heat treatment. They can however be work hardened.

Solution treatment or annealing can be done by rapid cooling after heating to around 1100°C.

Weldability

Duplex stainless steelshave good weldability. All standard welding processes can be used. They are not quite as easily welded as the austenitic grades but low thermal expansion in duplex grades reduces distortion and residual stresses after welding. The recommended filler material for 2205 stainless steelis 2209.


Grade Reasons for choosing the grade

【H】 Ceramic lined pipe

Ceramic lined pipe is made through self-propagating high-temperature synthesis (SHS) technique.

【H】 Cast basalt lined steel pipe

Cast basalt lined steel pipe is composed by lined with cast basalt pipe, outside steel pipe and cement mortar filling between the two layers.

【H】 Ceramic Tile Lined Pipes

Ceramic tile lined pipes have very uniform coating of specially formulated ceramic material that is affixed to the inner of the pipe.

【H】 Rare earth alloy wear-resistant pipe

The material of the rare earth alloy wear-resistant pipe is ZG40CrMnMoNiSiRe, which is also the grade of rare earth alloy steel.

【H】 Tubes Erosion Shields

Tubes Erosion Shields are used to protect boiler tubing from the highly erosive effects of high temperatures and pressures thereby greatly extending tube life.

【H】 ASTM A213 T91 Alloy Tube

The ASTM A213 T91 seamless tubes are primarily used for boiler, superheater, and heat-exchanger.